NiII(TPA) as an efficient catalyst for alkane hydroxylation with m-CPBA.

نویسندگان

  • Takayuki Nagataki
  • Yoshimitsu Tachi
  • Shinobu Itoh
چکیده

A simple Ni(II)(TPA) complex [TPA = tris(2-pyridylmethyl)amine] has been demonstrated to act as an efficient turnover catalyst for alkane hydroxylation with m-CPBA (m-chloroperbenzoic acid), in which contribution of a NiO(+) (nickel-oxo) type active oxygen species is suggested.

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عنوان ژورنال:
  • Chemical communications

دوره 38  شماره 

صفحات  -

تاریخ انتشار 2006